Ti-6Al-4V Titanium (Grade 5)Anodizing

Can titanium be anodized?

Yes

Yes. Titanium anodizes to a thin, coloured oxide set by voltage (AMS 2488 Type III) or a grey anti-galling film (Type II). It is not a hard, thick coat like aluminum anodize.

Titanium anodizing grows the natural titanium dioxide film electrochemically, but the result is nothing like Type II or III on aluminum. The colour anodize most people mean (AMS 2488 Type III) is a film of only 30-300 nm, thinner than a wavelength of light; the colour comes from interference in that film, and the voltage sets it: roughly bronze at 10-20 V, purple and blue at 20-35 V, yellow and gold at 50-70 V, and greens and magentas above that. The film is transparent, adds no measurable dimension, and cannot chip or peel because it is the metal's own oxide. It is used for identification, part marking, medical instrument colour coding and appearance.

AMS 2488 Type II is the functional version: an alkaline anodize that builds a thicker (about 1-3 µm), matte grey oxide with good anti-galling and anti-fretting properties. It is common on aerospace fasteners, hinges and sliding titanium parts, usually followed by a dry-film lubricant. It also improves adhesion of primers and paints. Neither type provides wear resistance comparable to aluminum hardcoat; for a hard titanium surface, look at nitriding, PVD coatings or thermal oxidation instead. Type I (a high-temperature oxide) exists but is rarely used.

Colour anodizing is sensitive to surface prep. The colour is uniform only on a uniformly finished surface, so machining marks, grain and polish differences show as shade variation. Bead blasting or a chemical pickle before anodizing gives the most even result. The film is thin enough to wear off at contact points and to be scratched by steel tools, which is fine for marking and cosmetics but not for a surface that sees abrasion. Both types are done on Ti-6Al-4V, commercially pure grades and most other alpha-beta alloys; colour response is slightly different between alloys, so match alloys in a colour-matched set.

Anodizing for Ti-6Al-4V parts: where to send them

Attach a drawing (PDF or STEP) or describe the part; a U.S. shop that fits quotes it.

What to specify

  • AMS 2488 Type II (anti-galling, grey) or Type III (colour), never a MIL-A-8625 aluminum spec
  • For Type III: the colour by name and a target voltage or a reference sample, and the acceptable shade variation
  • Surface preparation before anodizing (bead blast, pickle or as-machined) since it sets colour uniformity
  • For Type II: whether a dry-film lubricant follows and to what spec
  • Masking on electrical contact surfaces if the oxide must not interfere (the film is a poor conductor)
  • Alloy and condition on the same drawing; colour response differs between Ti-6Al-4V and CP grades
  • Handling and packaging so the thin film is not scratched before assembly

Pitfalls

  • Calling out MIL-A-8625 Type II or III on a titanium drawing; those are aluminum specs and the finisher cannot meet them
  • Expecting a hardcoat: titanium anodize adds no wear resistance and no dimension
  • Blotchy colour from mixed surface finishes or alloy batches on a colour-matched set
  • Colour wearing through at handling and contact points; keep it off sliding surfaces
  • Scratching the film with steel tooling during assembly
  • Assuming corrosion improvement; titanium is already passive, the anodize is for colour, marking or galling

Frequently asked questions

How does titanium anodizing produce colour?
By light interference in a transparent oxide film tens to hundreds of nanometres thick. The anodizing voltage sets the thickness and the thickness sets the colour, from bronze around 15 V through blue, yellow and green to magenta above 70-90 V.
Is titanium anodizing as hard as aluminum hardcoat?
No. Aluminum Type III builds 25-75 µm of hard oxide; titanium colour anodize is under 0.3 µm and Type II about 1-3 µm. Neither adds wear resistance. For a hard titanium surface use nitriding, PVD or thermal oxidation.
What is AMS 2488 Type II used for?
A grey, matte anti-galling oxide on aerospace titanium fasteners, hinges and fittings, usually topped with a dry-film lubricant. It reduces fretting and galling between titanium parts and improves paint adhesion.

Read next

More about Ti-6Al-4V

Anodizing on other materials